Mr. Queen is Unavailable
Episode: 1x01 | Airdate: Nov 6, 2013
Roy Harper came to meet Oliver Queen but Felicity Smoak tells him to wait as Oliver is not available.
Season 1
Roy to the Rescue
Episode: 1x02 | Airdate: Nov 13, 2013
Detective Lance calls Felicity telling her that SCPD Laboratory is having blood samples of The Arrow then Felicity gives Roy Harper a job to break in SCPD Laboratory and get the samples.
Down the Rabbit Hole
Episode: 1x03 | Airdate: Nov 20, 2013
Roy Harper breaks in SCPD Laboratory to get blood samples of The Arrow.
The Sample
Episode: 1x04 | Airdate: Nov 27, 2013
Felicity Smoak helps Roy Harper escaping SCPD Laboratory.
Closing In
Episode: 1x05 | Airdate: Dec 4, 2013
Roy Harper escapes SCPD Laboratory getting the blood samples of The Arrow with the help of Felicity Smoak.
Heroic Deeds
Episode: 1x06 | Airdate: Dec 11, 2013
Roy Harper gives the blood samples to Felicity and felicity allows him to meet Oliver Queen.