Season 1 - Episode Guide

Thrush sends assassins after Waverly when he learns of an attempt on the life of a African dignitary. Napoleon thwarts the killers and heads out into the field with the ex-girlfriend of the industrialist, Andrew Vulcan, who is behind the attempt.

Solo investigates the curious death of an air force man in Iowa with scuba gear, and with the help of Jill Denison (Katherine Crawford) uncovers a plan by Clint Spinner (Slim Pickens) to steal a missile- plane from a secret base under a farm.

In Yugoslavia, Solo and Illya are aided by Marion Raven (Jill Ireland) in stopping Gervaise Ravel (Anne Francis) and her partners from using a fear gas to overthrow various governments. While two of them are captured, two of them escape, and the story continues in "The Giuoco Piano Affair"

Solo and Illya investigate a series of kidnappings that lead to a modern-day pirate ship run by Captain Shark (Robert Culp), who is filling his Noah's Ark with craftsmen from all walks of life to repopulate the world after the nuclear holocaust he feels is imminent. With the help of Harry Barnman (Herbert Anderson) and his wife Elsa (Sue Anne Langdon). Solo and Illya pose as shipwrecked sailors to in turn wreck his plans.

When a rare postage stamp at an auction reveals that a former SS scientist, Professor Amadeus, is still alive and experimenting with the secret of "suspended animation," Solo and Illya enlist the aid of college students Terry Brent (Brook Bundy) and Chuck Boskirk (Burt Brinckerhoff) to beat THRUSH agent Angelique (Janine Gray) to Amadeus's lab, where Solo is captured so his blood can be used to revive the suspended body of the Fuhrer.

In the Yucatan, THRUSH agent Walter Brach (Carroll O'Connor) brainwashes important people from many nations to be "time bombs" who will return to their jobs and do THRUSH's bidding. After eluding Brach's henchmen Chuke (Shuji J. Nozawa) and his leopards, Solo and housewife Chris Linnel (Joan O'Brien) enlist the aid of Mrs. Karda (Dovima), Brach's numerologist, to help them escape.

Solo and Illya use a complex deception to trap an evil diplomat.

Solo must prevent a war by learning who is responsible for launching fungus-spraying missiles that are destroying Russia's grain crop.

Solo races an enemy agent (Ricardo Montalban) for possession of a dead hero's medal bearing names of THRUSH operatives.

A kidnapped Solo learns a deposed Middle East ruler is brainwashing mob leaders to conquer the world.

In a tiny Balkan police state, an old flame talks a vacationing Solo into helping descredit a treacherous colonel.

THRUSH tries to rescue its top agent from Solo and Kuryakin, while Mr. Waverly takes a decoy agent over a different route.

Solo and Kuryakin attempt to steal $50 million which THRUSH has stashed in a vault under a casino; guest Dan O'Herlihy.

An U.N.C.L.E. agent is strangled aboard an airplane, which then crashes near Bombay, killing all passengers.

The agents race to find a hidden explosive planted in U.N.C.L.E. headquarters. Gust star: Richard Haydn.

Solo and Illya are ordered to help a legendary mercenary steal a diamond-filled, golden sceptre from a Middle East leader.

Illya investigates when Waverly's cousin is the latest victim in a series of fatal vicious dog attacks.